Publications

2019

 

76.

M. Orella, T. Z. H. Gani, J. V. Vermaas, M. L. Stone, E. M. Anderson, G. T. Beckham, F. R. Brushett, Y. Román-Leshkov

Lignin-KMC: A Toolkit for Simulating Lignin Biosynthesis

ACS Sustainable Chem. Eng., 2019

DOI: 10.1021/acssuschemeng.9b03534

75.

M. Gigli, J. A. Kowalski, B. J. Neyhouse, A. D'Epifanio, F. R. Brushett, S. Licoccia

Investigating the factors that influence resistance rise of PIM-1 membranes in nonaqueous electrolytes

Electrochemistry Communications, 2019

DOI: 10.1016/j.elecom.2019.106530

74.

S. Sen, S. M. Brown, M. Leonard, and F. R. Brushett

Electroreduction of carbon dioxide to formate at high current densities using tin and tin oxide gas diffusion electrodes

Journal of Applied Electrochemistry, 2019

49(9), 917-928

73.

T. Z. H. Gani, M. J. Orella, E. M. Anderson, M. L. Stone, F. R. Brushett, G. T. Beckham, and Y. Román-Leshkov

Computational evidence for kinetically controlled radical coupling during lignification

ACS Sustainable Chem. Eng., 2019

7(15), 13270-13277

72.

A. Forner-Cuenca, E. E. Penn, A. M. Oliveira, and F. R. Brushett

Exploring the Role of Electrode Microstructure on the Performance of Non-Aqueous Redox Flow Batteries

Journal of The Electrochemical Society, 2019

166(10), A2230-A2241

71.

J. L. Barton, A. I. Wixtrom, J. A. Kowalski, E. A. Qian, D. Jung, F. R. Brushett, and A. M. Spokoyny

Perfunctionalized Dodecaborate Clusters as Stable Metal-Free Active Materials for Charge Storage

ACS Appl. Energy Mater., 2019

2(7), 4907-4913

69.

N. H. Attanayake, J. A. Kowalski, K. V. Greco, M. D. Casselman, J. D. Milshtein, S. J. Chapman, S. R. Parkin, F. R. Brushett, and S. A. Odom

Tailoring Two-Electron-Donating Phenothiazines To Enable High-Concentration Redox Electrolytes for Use in Nonaqueous Redox Flow Batteries

Chemistry of Materials, 2019

31(12), 4353-4363

68.

J. L. Barton and F. R. Brushett

A One-Dimensional Stack Model for Redox Flow Battery Analysis and Operation

Batteries, 2019

5(1), 25

67.

M. M. Machovina, E. S. Ellis, T. J. Carney, F. R. Brushett, and J. L. DuBois

How a cofactor-free protein environment lowers the barrier to O2 reactivity

J. Biol. Chem., 2019

294(10), 3661-3669

2018

 

66.

K. V. Greco, A. Forner-Cuenca, A. Mularczyk, J. Eller, and F. R. Brushett

Elucidating the Nuanced Effects of Thermal Pretreatment on Carbon Paper Electrodes for Vanadium Redox Flow Batteries

ACS Appl. Mater. Interfaces, 2018

10(51), 44430-44442

65.

P. Bai, J. Guo, M. Wang, A. Kushima, L. Su, J. Li, F. R. Brushett, and M. Z. Bazant

Interactions between Lithium Growths and Nanoporous Ceramic Separators

Joule, 2018

2(11), 2434-2449

63.

J. L. Barton, J. D. Milshtein, J. J. Hinricher,
and F. R. Brushett

Quantifying the impact of viscosity on mass-transfer coefficients in redox flow batteries

Journal of Power Sources, 2018

399, 133-143

 

62.

V. Dieterich, J. Milshtein, J. Barton, T. Carney,
R. Darling, and F. Brushett

Estimating the Cost of Organic Battery Active Materials: A Case Study on Anthraquinone Disulfonic Acid

Translational Materials Research, 2018

5, 034001

61.

M. J. Orella, Y. Román-Leshkov, and F. R. Brushett

Emerging opportunities for electrochemical processing to enable sustainable chemical manufacturing

Current Opinion in Chemical Engineering, 2018

20, 159-167

2017

60.

S. Sen, M. Leonard, R. Radhakrishnan, S. Snyder, B. Skinn, D. Wang, T. Hall, E. J. Taylor, and F. R. Brushett

Pulse Plating of Copper onto Gas Diffusion Layers for the Electroreduction of Carbon Dioxide 

MRS Advances, 2017

3(23), 1277-1284

59.

J. D. Milshtein, R. M. Darling, J. Drake, M. L. Perry, and F. R. Brushett

The Critical Role of Supporting Electrolyte Selection on Flow Battery Cost 

Journal of The Electrochemical Society, 2017

164(14), A3883-A3895

58.

J. A. Kowalski, M. D. Casselman, A. P. Kaur, J. D. Milshtein, C. F. Elliott, S. Modekrutti, N. H. Attanayake, N. Zhang, S. R. Parkin, C. Risko, F. R. Brushett, and S. A. Odom 

A Stable Two-Electron-Donating Phenothiazine for Application in Nonaqueous Redox Flow Batteries 

Journal of Materials Chemistry A, 2017

5, 24371-24379 

57.

Z. Li, M. S. Pan, L. Su, P.-C. Tsai, A. F. Badel, J. M. Valle, S. L. Eiler, K. Xiang, F. R. Brushett, and Y.-M. Chiang

Air-Breathing Aqueous Sulfur Flow Battery for Ultralow-Cost Long-Duration Electrical Storage

Joule, 2017

1, 306-327

Featured as a Joule backstory and as the October 2017 cover art (left).

56.

E. V. Carino, D. J. Newman, J. G. Connell, C. Kim, and F. R. Brushett

Early Stage Anodic Instability of Glassy Carbon Electrodes in Propylene Carbonate Solvent Containing Lithium Hexafluorophosphate

Langmuir, 2017

33(43), 11911–11918

55.

L. Su, A. F. Badel, C. Cao, J. J. Hinricher, and F. R. Brushett

Toward an Inexpensive Aqueous Polysulfide-Polyiodide Redox Flow Battery

Industrial & Engineering Chemistry Research, 2017

56(35), 9783–9792

Invited paper

I&EC Research special issue for the 2017 Class of Influential Researchers

54.

J. D. Milshtein, J. L. Barton, T. J. Carney, J. A. Kowalski, R. M. Darling, and F. R. Brushett

Towards Low Resistance Nonaqueous Redox Flow Batteries

Journal of The Electrochemical Society, 2017

164(12), A2487-A2499

53.

S. Liu, M. Kok, Y. Kim, J. L. Barton, F. R. Brushett, and J. Gostick

Evaluation of Electrospun Fibrous Mats Targeted for Use as Flow Battery Electrodes

Journal of The Electrochemical Society, 2017

164(9), A2038-A2048

52.

J. D. Milshtein, K. M. Tenny, J. L. Barton, J. Drake, R. M. Darling, and F. R. Brushett

Quantifying Mass Transfer Rates in Redox Flow Batteries

Journal of The Electrochemical Society, 2017

164(11), E3265-E3275

JES Focus Issue on Mathematical Modeling of Electrochemical Systems at Multiple Scales in Honor of John Newman

One of the most downloaded in Q1 & Q2 2018!

51.

L. Su, M. Ferrandon, J. L. Barton, N. Upia de la Rosa, J. T. Vaughey, and F. R. Brushett

An investigation of 2,5-di-tertbutyl-1,4-bis(methoxyethoxy)benzene in ether-based electrolytes

Electrochimica Acta, 2017

246, 251-258

50.

B. Yan, N. M. Concannon, J. D. Milshtein, F. R. Brushett, and Y. Surendranath

A Membrane-Free Neutral pH Formate Fuel Cell Enabled by a Selective Nickel Sulfide Oxygen Reduction Catalyst

Angewandte Chemie International Edition, 2017

56(26), 7496-7499

Listed as a Very Important Paper in Angewandte Chemie International Edition

49.

T. J. Carney, S. J. Collins, J. S. Moore, and F. R. Brushett
Concentration-Dependent Dimerization of Anthraquinone Disulfonic Acid
and Its Impact on Charge Storage

Chemistry of Materials, 2017

29(11), 4801-4810

48.

W. Duan, J. Huang, J. A. Kowalski, I. A. Shkrob, M. Vijayakumar, E. Walter, B. Pan, Z. Yang, J. D. Milshtein, B. Li, C. Liao, Z. Zhang, W. Wang, J. Liu, J. S. Moore, F. R. Brushett, L. Zhang, and X. Wei

“Wine-Dark Sea” in an Organic Flow Battery: Storing Negative Charge in 2,1,3-Benzothiadiazole Radicals Leads to Improved Cyclability

ACS Energy Letters, 2017

2, 1156-1161

47.

D. D. Nevers, F. R. Brushett, and D. R. Wheeler

Engineering radical polymer electrodes for electrochemical energy storage

Journal of Power Sources, 2017

352, 226-244

46.

T. Salih, S. M. Brown, C. Kim, K. Carroll, F. R. Brushett, and A. Bumajdad

Cost Effective and Scalable Synthesis of Supported Au Nanoparticles for the Electroreduction of CO2 to CO

Science of Advanced Materials, 2017

9(6), 888-895

45.

J. D. Milshtein, S. L. Fisher, T. M. Breault, L. T. Thompson, and F. R. Brushett

Feasibility of a supporting salt free non-aqueous redox flow battery utilizing ionic active materials

ChemSusChem, 2017

10, 2080-2088

44.

S. Sen, B. Skinn, T. Hall, M. Inman, E. J. Taylor, and F. R. Brushett

Pulsed Electrodeposition of Tin Electrocatalysts onto Gas Diffusion Layers for Carbon Dioxide Reduction to Formate

MRS Advances, 2017

2(8), 451-458

 

43.

J. D. Milshtein, A. P. Kaur, M. D. Casselman, J. A. Kowalski, S. Modekrutti, P. Zhang, N. H. Attanayake, C. F. Elliott, S. R. Parkin, C. Risko, F. R. Brushett, and S. A. Odom

High current density, long duration cycling of soluble organic active species for non-aqueous redox flow batteries

Energy & Environmental Science, 2016

9, 3531-3543

2016

R. Dmello, J. D. Milshtein, F. R. Brushett, and K. C. Smith

Cost-Driven Materials Selection Criteria for Redox Flow Battery Electrolytes

Journal of Power Sources, 2016, 330, 261-272.

42.

42.

R. Dmello, J. D. Milshtein, F. R. Brushett, and K. C. Smith

Cost-Driven Materials Selection Criteria for Redox Flow Battery Electrolytes

Journal of Power Sources, 2016, 330, 261-272.

42.

R. Dmello, J. D. Milshtein, F. R. Brushett, and K. C. Smith

Cost-Driven Materials Selection Criteria for Redox Flow Battery Electrolytes

Journal of Power Sources, 2016

330, 261-272

41.

P. Bai, J. Li, F. R. Brushett, and M. Z. Bazant

Transition of lithium growth mechanisms in liquid electrolytes

Energy & Environmental Science, 2016

9, 3221-3229

40.

J. A. Kowalski, L. Su, J. D. Milshtein, and F. R. Brushett

Recent advances in molecular engineering of redox active organic molecules for nonaqueous flow batteries

Current Opinion in Chemical Engineering, 2016

13, 45-52

Invited Review

39.

J. Huang, B. Pan, W. Duan, X. Wei, R. S. Assary, L. Su, F. R. Brushett, L. Cheng, C. Liao, M. S. Ferrandon, W. Wang, Z. Zhang, A. K. Burrell, L. A. Curtiss, I. A. Shkrob, J. S. Moore, and L. Zhang

The lightest organic radical cation for charge storage in redox flow batteries

Scientific Reports, 2016

6, 32102

38.

S. Burlatsky, R. M. Darling, D. Novikov, V. V. Atrazhev, V. I. Sultanov, T. Y. Astakhova, L. Su, and F. R. Brushett

Molecular Dynamics Modeling of the Conductivity of Lithiated Nafion Containing Nonaqueous Solvents

Journal of The Electrochemical Society, 2016

163, A2232-A2239

37.

S. M. Laramie, J. D. Milshtein, T. M. Breault, F. R. Brushett, and L. T. Thompson

Performance and cost characteristics of multi-electron transfer common ion exchange non-aqueous redox flow batteries

Journal of Power Sources, 2016

327, 681-692

36.

J. D. Milshtein, J. L. Barton, R. M. Darling, and F. R. Brushett

4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl as a model organic redox active compound for nonaqueous flow batteries

Journal of Power Sources, 2016

327, 151-159

35.

K. Carroll, T. Burger, L. Langenegger, S. Chavez, S. T. Hunt, Y. Roman-Leshkov, and F. R. Brushett

Electrocatalytic Hydrogenation of Oxygenates using Earth-Abundant Transition-Metal Nanoparticles under Mild Conditions 

ChemSusChem, 2016

9, 1904-1910

34.

J. Han, M. Wang, P. Bai, F. R. Brushett, and M. Z. Bazant

Dendrite Suppression by Shock Electrodeposition in Charged Porous Media 

Scientific Reports, 2016

6, 28054

33.

E. Chenard, A. Sustrino, L. Zhu, R. S. Assary, J. A. Kowalski, J. L. Barton, J. A. Bertke, D. L. Gray, F. R. Brushett, L. A. Curtiss, and J. S. Moore

Synthesis of Pyridine- and Pyrazine-BF3 Complexes and Their Characterization in Solution and Solid State

Journal of Physical Chemistry C, 2016

120, 8461-8471

32.

E. V. Carino, J. Staszak-Jirkovsky, R. S. Assary, L. A. Curtiss, N. M. Markovic, and F. R. Brushett

Tuning the Stability of Organic Active Materials for Nonaqueous Redox Flow Batteries via Reversible, Electrochemically Mediated Li+ Coordination

Chemistry of Materials, 2016

28, 2529-2539

31.

W. Duan, R. S. Vemuri, J. D. Milshtein, S. Laramie, R. D. Dmello, J. Huang, D. Hu, M. Vijayakumar, W. Wang, J. Liu, R. M. Darling, L. Thompson, K. Smith, J. S. Moore, F. R. Brushett, and X. Wei

A symmetric organic-based nonaqueous redox flow battery and its state of charge diagnostics by FTIR 

Journal of Materials Chemistry A, 2016

4, 5448-5456

Included in the themed collection: 2016 Journal of Materials Chemistry A HOT Papers

30.

L. Su, R. M. Darling, K. G. Gallagher, W. Xie, J. L. Thelen, A. F. Badel, J. L. Barton, K. J. Cheng, N. P. Balsara, J. S. Moore and F. R. Brushett. 

An Investigation of the Ionic Conductivity and Species Crossover of Lithiated Nafion 117 in Nonaqueous Electrolytes 

Journal of The Electrochemical Society, 2016

163(1), A5253-A5262

JES Focus Issue on Redox Flow Batteries–Reversible Fuel Cells

29.

R. M. Darling, K. G. Gallagher, W. Xie, L. Su, and F. R. Brushett

Transport Property Requirements for Flow Battery Separators

Journal of The Electrochemical Society, 2016

163(1), A5029-A5040

JES Focus Issue on Redox Flow Batteries–Reversible Fuel Cells

28.

J. D. Milshtein, L. Su, C. Liou, A. F. Badel, and F. R. Brushett

Voltammetry study of quinoxaline in aqueous electrolytes

Electrochimica Acta, 2015

180, 695-704

2015

 

27.

F. R. Brushett, A. N. Jansen, J. T. Vaughey, L. Su, J. D. Milshtein
Materials for use with aqueous redox flow batteries and related methods and systems
Massachusetts Institute of Technology & UChicago Argonne LLC, assignees. Patents US 2015/0236543 A1 & WO 2015/126907 A1.
August 20, 2015

26.

J. Huang, L. Su, J. A. Kowalski, J. L. Barton, 

M. Ferrandon, A. K. Burrell, F. R. Brushett and L. Zhang

A subtractive approach to molecular engineering of dimethoxybenzene-based redox materials for non aqueous flow batteries

Journal of Materials Chemistry A, 2015

3, 14971-14976

25.

23.

E. V. Carino, C. E. Diesendruck, J. S. Moore, L. A. Curtiss, R. S. Assary, and F. R. Brushett

BF3-promoted electrochemical properties of quinoxaline in propylene carbonate

Royal Society of Chemistry Advances, 2015

5(24), 18822-18831

2014

22.

R. Darling, K. G. Gallagher, J. A. Kowalski, S. Ha, and F. R. Brushett

Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries

Energy & Environmental Science, 2014

7, 3459-3477

21.

L. Su, M. Ferrandon, J. A. Kowalski, J. T. Vaughey, and F. R. Brushett 

Electrolyte Development for Non-Aqueous Redox Flow Batteries Using a High-Throughput Screening Platform

Journal of The Electrochemical Society, 2014

161(12), A1905-A1914

20.

R. S. Assary, F. R. Brushett, L. A. Curtiss

Reduction potential predictions of some aromatic nitrogen-containing molecules

Royal Society of Chemistry Advances, 2014

4, 57442-57451

19.

F. R. Brushett, L. Trahey, X. Xiao, and J. T. Vaughey

Full-Field Synchrotron Tomography of Nongraphitic Foam and Laminate Anodes for Lithium-Ion Batteries

ACS Applied Materials & Interfaces, 2014

6, 4524–4534 

2013-2006

18.

M. S, Naughton, C. E. Tornow, Y. Bonita, H. R. M. Jhong, F. R. Brushett, A. A. Gewirth, and P. J. A. Kenis

In-situ measurement of ethanol tolerance in an operating fuel cell

International Journal of Hydrogen Energy, 2013

38, 8980-8991

19.

R. Darling, K.G. Gallagher, J.A. Kowalski, S. Ha, and F.R. Brushett

Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries

Energy & Environmental Science, 2014,7, 3459-3477

17.

H. R. M. Jhong, F. R. Brushett, and P. J. A. Kenis

The Effects of Catalyst Layer Deposition Methodology on Electrode Performance 

Advanced Energy Materials., 2013

3, 589-599

Front cover of the Advanced Energy Materials Vol. 3 No. 5 on 5/201

16.

F. R. Brushett, J. T. Vaughey, and A. N. Jansen 

An All-Organic Non-aqueous Lithium-Ion Redox Flow Battery 

Advanced Energy Materials, 2012

2, 1390-1396 

15.

M. R. Thorson, F. R. Brushett, C. J. Timberg, and P. J. A. Kenis

Design rules for electrode arrangement in an air-breathing alkaline direct methanol laminar flow fuel cell

Journal of Power Sources, 2012

218, 28-33 

14.

F. R. Brushett, M. S. Naughton, J. W. D. Ng, L. L. Yin, and P. J. A. Kenis

Analysis of Pt/C electrode performance in a flowing-electrolyte alkaline fuel cell

International Journal of Hydrogen Energy, 2012

37, 2559-2570

13.

H. R. M. Jhong, F. R. Brushett, L. L. Yin, D. Stevenson, and P. J. A. Kenis

Combining Structural and Electrochemical Analysis of Electrodes using Micro-Computed Tomography and a Microfluidic Fuel Cell

Journal of The Electrochemical Society, 2012

159, B292-B298

Highlighted in: Tech Highlights in ECS Interface Summer Edition 

12.

P. O. Lopez-Montesinos, N. Yossakda, A. Schmidt, F. R. Brushett, W. Pelton, and P. J. A. Kenis

Design, fabrication, and characterization of a planar, silicon-based, monolithically integrated micro laminar flow fuel cell with a bridge-shaped microchannel cross-section

Journal of Power Sources, 2011

196, 4638-4645 

11.

M. S. Naughton, F. R. Brushett, and P. J. A. Kenis

Carbonate resilience of flowing electrolyte-based alkaline fuel cells

Journal of Power Sources, 2011

191, 1762-1768 

10.

F. R. Brushett, M. S. Thorum, N. S. Lioutas, M. S. Naughton, C. Tornow, H. R. M. Jhong, A. A. Gewirth, and P. J. A. Kenis

A Carbon-Supported Copper Complex of 3,5-Diamino-1,2,4-triazole as a Cathode Catalyst for Alkaline Fuel Cell Applications

Journal of The American Chemical Society, 2010

132(35), 12185-12187

9.

F. R. Brushett, H. T. Duong, J. W. D. Ng, R. L. Behrens, A. Wieckowski, and P. J. A. Kenis

Investigation of Pt, Pt3Co and Pt3Co/Mo cathodes for the ORR in a Microfluidic H2/O2 Fuel Cell

Journal of The Electrochemical Society, 2010

157, B837-B845

8.

S. K. Yoon, R. S. Jayashree, F. R. Brushett, P. O. Lopez-Montesinos, D. Natarajan, L. J. Markoski, and P. J. A. Kenis

On the Performance of Membraneless Laminar Flow-Based Fuel Cells

Journal of Power Sources, 2010

195, 3569-3578 

7.

F. R. Brushett, R. S. Jayashree, W. P. Zhou, and P. J. A. Kenis

Investigation of Fuel and Media Flexible Laminar Flow-Based Fuel Cells

Electrochimica Acta, 2009

54, 7099-7105 

6.

A. S. Hollinger, F. R. Brushett, L. J. Markoski, and P. J. A. Kenis

Scaling and Manufacturing of Laminar Flow-Based Fuel Cells

Proceedings of MicroTAS Conference, Groningen, Netherlands, 2010, 1748-1750 

5.

F. R. Brushett, P. J. A. Kenis, and A. Wieckowski

New Concepts in the Chemistry and Engineering of Low-Temperature Fuel Cells

Fuel Cell Science: Theory, Fundamentals, and Bio-catalysis, A. Wieckowski & J.K. Norskov, editors, (John Wiley & Sons, Inc.), 2010, 565-610

4.

F. R. Brushett, W. P. Zhou, R. S. Jayashree, and P. J. A. Kenis

Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform

Journal of The Electrochemical Society, 2009

156, B565-B571 

3.

F. R. Brushett, A. S. Hollinger, L. J. Markoski, and P. J. A. Kenis

Microfluidic Fuel Cells as Microscale Power Sources and Analytical Platforms

Proceedings of ASME 2009 2nd Micro/Nanoscale Heat & Mass Transfer International Conference, Shanghai, China

2.

F. R. Brushett, M. Mitchell, R. S. Jayashree, W. P. Zhou, and P. J. A. Kenis

Vapor Feed Direct Methanol Fuel Cell with Flowing Electrolyte

ECS Transactions, 2007

11, 1419-1424

1.

F. A. Ngantung, P. G. Miller, F. R. Brushett, G. L. Tang, and D. I. C. Wang

RNA Interference of Sialidase Improves Glycoprotein Sialic Acid Content Consistency

Biotechnology and Bioengineering, 2006

95, 106-119